MS/SE is better for defence as it provides more coverage, while MS/EQ is better on offence like you said because they're the same type so against good matchups both will be super effective.
MS/EQ should be better on offence too because there's more types you're advantageous against. The types that rock is SE against that ground is not (ice, flying and bug), you wouldn't use a Rhydon for anyway.
Also it really grinds my gears when someone thinks a charge move is good because it deals high DPS. Your overall DPS is what matters, because you cannot only use your charge move. Because of this, charge moves that deal high DPS for longer are better than charge moves that deal the same (or slightly more) DPS over a shorter period of time, because longer moves make up a larger percentage of an overall damage cycle (your damage from quick moves and charge moves combined) and therefore mean they increase the average DPS more.
If you had a charge move that did 1 damage in 0.001s it would have 1000 DPS but it'd still be a shit charge move because it would have almost no impact on your overall DPS.