This is a no brainer. You want the best defense possible, since Blissey's defense is so low, as well as attack. I think it's pretty clear that a 10 stamina 15 attack 15 defense Blissey is better than a 15 stamina 14 attack 14 defense Blissey.
So power up the 98% one with 14 Stamina, and don't look back. And when you have enough candy and dust, power the other 98% one up too - it will also be great.
All that said, the difference in IVs for Blissey is pretty small, and all of them are good.