GamePress has both IT/C and DT/C listed as the best movesets for Steelix as a defender. Though, I'd say DT/C would be a better option for Steelix for neutral coverage against Pokemon that can counter him and resist his Steel-type moves. You should also consider which quick move you would want to give your Steelix depending on what weather you normally get. If it's usually windy around you, DT would probably suffice. If it's snowy, then IT.
SIDENOTE: Rayquaza is most likely around the corner, so that means Steelix and Aggron will most likely be the best counters to the legendary dragon. Steelix will probably be able to put in maximum damage output against Rayquaza with DT/C, so also consider this, as well.