I prefer Flamethrower > Overheat on Charizard and Flareon, me personally, I wouldn't
As you know, overheat has a higher dps, but I prefer the nearly half cooldown (2.2s v 4s) for dodging purposes and as well there are scenarios where a defender/boss gets KOd or Entei gets KOd before it can fully charge and fire off an overheat, another reason why I prefer flamethrower