I'm in a similar situation - two Raikou at level 36, one at 31, and want to power up my old Jolteon a bit more to join the Suicune team.
To figure out the breakpoints, you can use pokebattler. For example, if I enter my level 33 Jolteon 15/11/15 in as the attacker then set Suicine as the defender, you can see that I need to bring it up to level 35 to hit 5 damage with Thunder Shock. You check this by viewing the Combat Log.
Alternatively, there is a spreadsheet that someone posted on Reddit Silph Road to check all breakpoints quickly.