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Togetic
Yeah, nightmare, threw 5 GRBs on it, curved, and ran away, what a waste of balls and those berries. Level 28 for reference.
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I have wasted 30 ultra balls and 10 blue balls with normal razz berrys on my second Togetic encounter (I could not do curveballs yet) - and then I wanted to spin a Pokéstop after which it was gone.
My first Togetic was caught in 1 ball from a bus ride.
My third Togetic was caught after escaping from 2 Golden Razz + Ultra + curve throws.