The [ To get a wanted CM out of three, you should have 2 Charged TMs ]
Is an ''a priori expected value'', infact you can only use ONE TM at time, so if you fail the first one , then you still got a 50% chance to get what you want.
So the overall 2/3 chance is a not precise prediction.
Still I might stock 2 charged TM to try get C on one of my SE Tyranitar...(who had Fire Blast, I already used a TM onto him!).