Palkia is tankier than Ray, but not "better." He is a top 3 dragon type so worth investing if you don't have enough Ray or Dragonite. I will power up my best one just because he looks cool and is useful, with the potential dual charge moves Draco and Hydro Pump. If you have no other place to put rare candies he is worthy IMO.
PS - still not sure why he is so tiny though...