If pokebattler sims are correct, no rejoin duo is extremely difficult to pull off and doesn't actually involve Groudon for most movesets. Assuming BF bonus:
Iron Head: You need both players to have 6 maxed Kyogres. Against Fire Spin you also need good luck.
Fire Blast: Both players need either 6 maxed Rhyperior (Fire Spin) or a mix of maxed Rhyperior and Rhydon (Bug Bite).
Stone Edge: Both players having 6 maxed Rhydon can pull it off with luck. Any Rhyperiors or Groudons help, probably 1 each is enough to make it fairly consistent.