the lower defense = better DPS is a myth. Your blastoise are good raid attackers, but I wouldn't worry about IV's too much, they are good as attack is really all that matters, and you still have a good few months to stock up for mudkip when it gets a CD (I highly doubt niantic'd cut off the hoenn starters from the moves)
for PvP, blastoise is better than feraligatr in both great and ultra leagues.