Slowbro only if he has confusion/psychic and is at least 85% or better. Otherwise a total waste of candy/dust.
Moves don't matter so much on Exeggutor. Psychic/confusion best, but others will work for defense. Any level 30 Exeggutor that is at least 70% IV I would power up to around 2,400 CP. Any Exeggutor over 90% I would power up to your max level every time you level up.
Venusaur is garbage. If you already have 10 to 20 top tier defenders then sure go ahead with Venusaur but otherwise save your dust/candy for top tier defenders.